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Bromine atoms are even more efficient catalysts; hence brominated CFCs are also regulated. Every permutation of fluorine, chlorine and hydrogen based on methane and ethane has been examined and most have been commercialized.
Furthermore, many examples are known for higher numbers of carbon as well as related compounds containing bromine. Uses include refrigerants , blowing agents , propellants in medicinal applications and degreasing solvents.
Billions of kilograms of chlorodifluoromethane are produced annually as precursor to tetrafluoroethylene , the monomer that is converted into Teflon.
A special numbering system is used for fluorinated alkanes, prefixed with Freon-, R-, CFC- and HCFC-, where the rightmost value indicates the number of fluorine atoms, the next value to the left is the number of hydrogen atoms plus 1, and the next value to the left is the number of carbon atoms less one zeroes are not stated , and the remaining atoms are chlorine.
It is therefore CCl 2 F 2. The resulting value will give the number of carbons as the first numeral, the second numeral gives the number of hydrogen atoms, and the third numeral gives the number of fluorine atoms.
The rest of the unaccounted carbon bonds are occupied by chlorine atoms. The value of this equation is always a three figure number.
An easy example is that of CFC, which gives: The main advantage of this method of deducing the molecular composition in comparison with the method described in the paragraph above is that it gives the number of carbon atoms of the molecule.
Freons containing bromine are signified by four numbers. Isomers , which are common for ethane and propane derivatives, are indicated by letters following the numbers:.
Carbon tetrachloride CCl 4 was used in fire extinguishers and glass "anti-fire grenades" from the late nineteenth century until around the end of World War II.
Experimentation with chloroalkanes for fire suppression on military aircraft began at least as early as the s. Freon is a trade name for a group of CFCs which are used primarily as refrigerants , but also have uses in fire-fighting and as propellants in aerosol cans.
Bromomethane is widely used as a fumigant. Dichloromethane is a versatile industrial solvent. In the late s, Thomas Midgley, Jr.
In searching for a new refrigerant, requirements for the compound were: In a demonstration for the American Chemical Society , Midgley flamboyantly demonstrated all these properties by inhaling a breath of the gas and using it to blow out a candle  in During World War II , various chloroalkanes were in standard use in military aircraft, although these early halons suffered from excessive toxicity.
Nevertheless, after the war they slowly became more common in civil aviation as well. In the s, fluoroalkanes and bromofluoroalkanes became available and were quickly recognized as being highly effective fire-fighting materials.
Much early research with Halon was conducted under the auspices of the US Armed Forces, while Halon was, initially, mainly developed in the UK.
By the late s they were standard in many applications where water and dry-powder extinguishers posed a threat of damage to the protected property, including computer rooms, telecommunications switches, laboratories, museums and art collections.
Beginning with warships , in the s, bromofluoroalkanes also progressively came to be associated with rapid knockdown of severe fires in confined spaces with minimal risk to personnel.
By the early s, bromofluoroalkanes were in common use on aircraft, ships, and large vehicles as well as in computer facilities and galleries.
However, concern was beginning to be expressed about the impact of chloroalkanes and bromoalkanes on the ozone layer. The Vienna Convention for the Protection of the Ozone Layer did not cover bromofluoroalkanes as it was thought, at the time, that emergency discharge of extinguishing systems was too small in volume to produce a significant impact, and too important to human safety for restriction.
Since the late s, the use of CFCs has been heavily regulated because of their destructive effects on the ozone layer. After the development of his electron capture detector , James Lovelock was the first to detect the widespread presence of CFCs in the air, finding a mole fraction of 60 ppt of CFC over Ireland.
In a self-funded research expedition ending in , Lovelock went on to measure CFC in both the Arctic and Antarctic, finding the presence of the gas in each of 50 air samples collected, and concluding that CFCs are not hazardous to the environment.
The experiment did however provide the first useful data on the presence of CFCs in the atmosphere. This was later superseded by broader regulation by the EPA under the Clean Air Act to address stratospheric ozone depletion .
By , in response to a dramatic seasonal depletion of the ozone layer over Antarctica , diplomats in Montreal forged a treaty, the Montreal Protocol , which called for drastic reductions in the production of CFCs.
In , diplomats met in London and voted to significantly strengthen the Montreal Protocol by calling for a complete elimination of CFCs by the year By the year , CFCs should have been completely eliminated from developing countries as well.
Because the only CFCs available to countries adhering to the treaty is from recycling, their prices have increased considerably.
A worldwide end to production should also terminate the smuggling of this material. The report estimated between 7, and 14, tonnes of CFCs are smuggled annually into developing countries.
The cost of replacing the equipment of these items is sometimes cheaper than outfitting them with a more ozone-friendly appliance.
Additionally, CFC smuggling is not considered a significant issue, so the perceived penalties for smuggling are low. In public attention was drawn to the issue, that at an unknown place in east Asia an estimated amount of By the time of the Montreal Protocol , it was realised that deliberate and accidental discharges during system tests and maintenance accounted for substantially larger volumes than emergency discharges, and consequently halons were brought into the treaty, albeit with many exceptions.
While the production and consumption of CFCs are regulated under the Montreal Protocol, emissions from existing banks of CFCs are not regulated under the agreement.
In , there were an estimated 5, kilotons of CFCs in existing products such as refrigerators, air conditioners, aerosol cans and others.
In the United States banned the use of CFCs such as Freon in aerosol cans, the beginning of a long series of regulatory actions against their use.
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